Nickel & Cobalt Alloys

Alloy 690 Supply Detail

Category

  • Bar and Rod

  • Plate and Sheet

  • Strip

  • Pipe and Tube

  • Wire

  • Welding

  • Powder Material

  • Cast Products

  • Forged Products

  • Fittings

  • Fastening

    Forms & Sizes

    Round Bar:
    φ2–500 mm, 1–6 m length

    Flat/Square Bar:
    4–100 mm thickness/width

    Hex Bar:
    A/F 3–100 mm

    Hollow Bar:
    OD 20–300 mm

    Forms & Sizes

    Sheet:
    0.3–6 mm thickness

    Medium Plate:
    6–25 mm thickness

    Heavy Plate:
    25–100 mm thickness

    Forms & Sizes

    Standard Strip:
    0.05–3 mm thick,
    10–600 mm wide

    Precision strip:
    0.01–0.5 mm thick,
    tight tolerance ±0.005 mm

    Foil:
    0.005–0.1 mm thick

    Forms & Sizes

    Seamless Tube:
    OD 6–450 mm,
    WT 1–50 mm,
    1–12 m length

    Welded Tube:
    OD 10–600 mm,
    WT 1–20 mm

    Capillary Tube:
    OD 1–10 mm,
    WT 0.1–2 mm

    Forms & Sizes

    Wire Form:
    Cold Drawn Wire,
    Bright Wire,
    Spring Wire,
    Fine Wire,
    Ultra-fine Wire

    General Diameter:
    φ0.1–10 mm

    Coil Weight:
    50–500 kg,
    customizable tolerance

    Forms & Sizes

    Solid Wire:
    φ0.8–4.0 mm

    Flux-cored Wire:
    φ1.2–4.0 mm

    Welding Rod:
    φ2.0–5.0 mm

    Forms & Sizes

    Powder Form:
    AM 3D Printing Powder,
    Spherical Powder,
    Gas-atomized Powder,
    Water-atomized Powder

    Particle Size:
    10–150 μm

    Sphericity:
    ≥90% for AM grade

    Forms & Sizes

    Cast Ingot:
    φ200–800 mm

    Precision Casting:
    min wall 0.5 mm

    Cast Pipe:
    OD 100–600 mm,
    WT 10–50 mm

    Forms & Sizes

    Forged Bar:
    Φ35–500 mm

    Forged Ring:
    OD 200–2000 mm

    Forging Weight:
    1–5000 kg

    Forms & Sizes

    Fittings Form:
    Elbow, Tee, Reducer, Flange, Cap, Outlet, Lap Joint

    Size range:
    1/2''–24'' (DN15–DN600)

    Wall thickness:
    Sch10–Sch160, STD, XS, XXS

    Pressure Class:
    150–2500 LB

    Forms & Sizes

    Fastening Form:
    Bolt, Nut, Screw, Stud, Washer, Pin, Rivet

    Metric: M3–M64

    Imperial: #4–2.5''

    Length: 6–500 mm

Alloy 690 Product Description

Overview

Alloy 690 is a single-phase, austenitic high-chromium nickel–chromium–iron alloy offering outstanding resistance to corrosive aqueous media and high-temperature atmospheres. This datasheet presents the material within the Alloy trade-name designation system.

Its very high chromium content (around 30%) gives outstanding resistance to oxidising chemicals and to high-temperature oxidising gases, while the high nickel content imparts resistance to chloride-induced stress-corrosion cracking and to caustic (sodium hydroxide) solutions. The alloy has high strength, good metallurgical stability and favorable fabrication characteristics. The low carbon content minimises grain-boundary carbide precipitation, preserving corrosion resistance in the heat-affected zones of welded joints.

Resistance to oxidising acids is exceptional, and the alloy resists nitric and nitric/hydrofluoric acid mixtures, sulphidation and high-temperature oxidation. It is the standard material for pressurized-water-reactor steam generator tubing, and is widely used in nitric acid production, pickling installations, and components for high-temperature oxidising and carburising environments, with operating capability up to approximately 1000 °C.

1. Physical Properties

Property Value Unit
Density 8.19 g/cm³
Melting range 1343–1377 °C
Elastic modulus 211 GPa
Coefficient of thermal expansion (20–100 °C) 14.0 µm/m·°C
Maximum operating temperature ~1000 °C
Structure Single-phase austenitic (FCC)

2. Chemical Composition (wt %)

Element Symbol Min % Max % Role in Alloy
Nickel Ni 58.0 Austenitic FCC matrix; SCC + caustic resistance
Chromium Cr 27.0 31.0 Oxidation + oxidising-acid resistance; passive film
Iron Fe 7.0 11.0 Solid-solution element
Manganese Mn 0.50 Deoxidiser
Silicon Si 0.50 Deoxidiser
Copper Cu 0.50 Residual
Carbon C 0.05 Low; minimises HAZ carbide precipitation
Sulphur S 0.015 Residual impurity

3. Mechanical Properties

Typical values; confirm against the mill test certificate for each delivery.

Condition Tensile strength Operating temperature
Annealed ≥586 MPa (≥85 ksi) Up to ~1000 °C
Annealed (0.2% yield) ≥240 MPa (≥35 ksi)
Elastic modulus 211 GPa

The alloy is a single-phase solid-solution material; it is not age-hardenable. Higher strength is obtained by cold work. Typical annealed elongation is ≥30%.

4. Corrosion Resistance

Environment Performance Notes
Nitric acid (HNO₃) Outstanding Very high chromium content
Nitric / hydrofluoric mixtures Outstanding Pickling installations
Caustic (NaOH) Outstanding High nickel content
Chloride stress-corrosion cracking Outstanding High nickel content
Pitting and crevice corrosion Very Good High chromium content
High-temperature oxidation Outstanding Stable Cr₂O₃ scale
Carburisation / nitridation Very Good High Cr + Ni

5. Heat Treatment

The alloy is a single-phase, solid-solution material and is NOT age-hardenable. Heat treatment is for solution annealing only.

Solution Anneal Purpose: Dissolves secondary phases, restores maximum corrosion resistance and ductility, recrystallises cold-worked structure. Typically 1040–1100 °C followed by rapid cooling (water quench) to retain the single-phase structure. A thermal treatment (e.g. ~715 °C) is sometimes applied to nuclear tubing to optimise the grain-boundary carbide structure and stress-corrosion-cracking resistance.

Cold work is used to increase strength where required; a subsequent solution anneal removes the effects of cold work.

6. Weldability and Joining

Excellent weldability; the low carbon content preserves corrosion resistance in the heat-affected zone. Matched-composition welding products give as-welded resistance in oxidising and caustic environments.

Welding Process Applicability Filler / Consumable
GTAW / TIG Excellent AWS A5.14 ERNiCrFe-7
GMAW / MIG Excellent AWS A5.14 ERNiCrFe-7
SMAW / stick Excellent AWS A5.11 ENiCrFe-7 electrode

The welding products are also used for dissimilar-metal and overmatched welding. No post-weld heat treatment is normally required.

7. Machinability and Fabrication

Machining Guidelines

Parameter Recommendation
Work hardening High rate (typical of Ni-Cr-Fe alloys); rigid setup, sharp tooling, positive rake
Cutting Low speed, sufficient feed/depth to cut below the work-hardened layer
Coolant Ample flood coolant
Preferred condition Solution-annealed

Forming Processes

Process Notes
Cold forming Readily cold-formed; high work-hardening rate; intermediate solution anneal for heavy reductions
Hot forming ~1150–950 °C; followed by rapid cooling to retain single-phase structure
Tube / bar Standard product forms for steam generator and process service

8. Applications

Industry Typical Components Key Requirements
Nuclear power Steam generator tubes, tubesheets, baffles Chloride/caustic SCC resistance
Chemical processing Nitric acid reheaters, pickling tanks and coils Nitric / HF acid resistance
Heat treatment Furnace components, retorts, fixtures High-temperature oxidation resistance
Petrochemical High-temperature process equipment Oxidation + carburisation resistance
Pollution control Acid-bearing process hardware Oxidising-media resistance

9. Available Product Forms and Standards

Product Form ASTM Standard ASME Code
Rod and bar ASTM B166 ASME SB-166
Plate, sheet and strip ASTM B168 ASME SB-168
Seamless pipe and tube ASTM B167 ASME SB-167
Welded tube ASTM B626 ASME SB-626
Forgings ASTM B564 ASME SB-564
Fittings ASTM B366 ASME SB-366
Welding consumables AWS A5.14 ERNiCrFe-7

Qualified for sour-service per ISO 15156-3 / NACE MR0175.

10. Comparison with Related Alloys (Alloy Trade-Name System)

Alloy Grade Ni % Cr % Fe % Other Best Used For
Alloy 690 ≥58 27–31 7–11 Nuclear SG tubing; nitric acid; high-temp oxidation
Alloy 600 ≥72 14–17 6–10 General Ni-Cr-Fe; high-temperature service
Alloy 601 58–63 21–25 bal Al 1–1.7 High-temperature oxidation resistance
Alloy 625 ≥58 20–23 ≤5 Mo 8–10; Nb 3.15–4.15 Seawater; chemical process; high strength
Alloy 800H 30–35 19–23 ≥39.5 High-temperature Fe-Ni-Cr

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