Alloy W is a nickel-molybdenum-chromium solid-solution-strengthened superalloy developed primarily as a filler metal for welding dissimilar alloys. This datasheet presents the material within the American (ASTM / ASME / UNS) standard system.
Developed primarily as a filler metal, Alloy W displays excellent dissimilar-welding characteristics and is widely used for joining dissimilar solid-solution-strengthened nickel alloys in the gas-turbine and aerospace industries. Its high molybdenum content provides solid-solution strength and good resistance to reducing media, while the chromium addition contributes oxidation resistance; the low carbon content minimises grain-boundary precipitation, so reliable welds can be made without post-weld heat treatment. The properties of dissimilar weld joints made with alloy W depend on the alloys being joined but are generally acceptable for a wide variety of combinations. It is supplied in the solution heat-treated condition.
Typical applications include filler metal for gas-metal-arc and gas-tungsten-arc welding of dissimilar nickel alloys and stainless steels in gas-turbine, aerospace and chemical-process industries, and a limited number of wrought ring-type components in older gas-turbine engines.
| Property | Value | Unit |
|---|---|---|
| Density | 9.03 | g/cm³ |
| Melting range | 1300–1360 | °C |
| Elastic modulus | 218 | GPa |
| Coefficient of thermal expansion (20–100 °C) | 11.3 | µm/m·°C |
| Thermal conductivity (20 °C) | 11.4 | W/m·K |
| Specific heat (20 °C) | 381 | J/kg·K |
| Structure | Austenitic (FCC), single phase | — |
| Element | Symbol | Min % | Max % | Role in Alloy |
|---|---|---|---|---|
| Nickel | Ni | Balance | — | Base element |
| Molybdenum | Mo | 23.0 | 26.0 | Solid-solution strengthening; reducing-media resistance |
| Chromium | Cr | 4.0 | 6.0 | Oxidation resistance |
| Iron | Fe | 4.0 | 7.0 | Solid-solution |
| Cobalt | Co | — | 2.50 | Residual |
| Vanadium | V | — | 0.60 | Minor |
| Manganese | Mn | — | 1.0 | Deoxidiser |
| Silicon | Si | — | 1.0 | Residual |
| Carbon | C | — | 0.12 | Carbide formation |
Solution heat-treated condition, typical values for UNS N10004.
| Condition | Property | Value |
|---|---|---|
| Solution annealed | Tensile strength (UTS) | ≥795 MPa (115 ksi) |
| Solution annealed | 0.2% yield strength | ≥360 MPa (52 ksi) |
| Solution annealed | Elongation at break | ≥30 % |
| Dissimilar weld joint | Properties | Depend on alloys joined |
| — | Elastic modulus | 218 GPa |
Confirm against the mill test report. As a filler metal, the alloy's value lies in the integrity of dissimilar weld joints rather than wrought-product strength.
| Environment | Performance | Notes |
|---|---|---|
| Reducing media | Good | High molybdenum content |
| High-temperature oxidation | Good | Chromium-bearing |
| Dissimilar weld-joint service | Very Good | Wide variety of nickel-alloy combinations |
| Radiation exposure | Good | Suitable for some nuclear applications |
| Strong oxidizing acids | Moderate | Lower chromium than C-type alloys |
The high molybdenum content gives good resistance to reducing media, while the chromium addition provides oxidation resistance; the alloy is most valued for the soundness and general acceptability of the dissimilar weld joints it produces rather than for service as a primary corrosion-resistant alloy.
A single-phase solid-solution alloy; not hardenable by precipitation. Properties are set by solution annealing.
Solution Anneal Solution anneal at approximately 1175 °C (2150 °F) and rapidly quench (water or rapid air cool) to dissolve secondary phases and retain a uniform structure. The alloy is not strengthened by heat treatment; cold work raises strength.
Excellent dissimilar-welding characteristics; this is the alloy's primary purpose. Used as filler metal for gas-metal-arc and gas-tungsten-arc welding of dissimilar solid-solution-strengthened nickel alloys and stainless steels. The low carbon content minimises grain-boundary precipitation, so welds are reliable without post-weld heat treatment.
| Welding Process | Applicability | Filler / Consumable |
|---|---|---|
| GTAW / TIG | Excellent | Alloy W filler (ERNiMo-3) |
| GMAW / MIG | Excellent | Alloy W filler (ERNiMo-3) |
| As filler metal | Primary use | Dissimilar nickel-alloy joints |
The alloy is itself a filler metal (AWS A5.14 ERNiMo-3); welds are reliable without post-weld heat treatment.
Machining Guidelines
| Parameter | Recommendation |
|---|---|
| Machinability | Difficult; work-hardens, rigid setups, sharp tooling |
| Speeds | Slow speeds, positive feeds, no dwelling |
| Coolant | Ample coolant |
Forming Processes
| Process | Notes |
|---|---|
| Cold forming | Limited; primarily supplied as wire / filler |
| Hot forming | ~1175 °C; solution anneal afterward |
| Industry | Typical Components | Key Requirements |
|---|---|---|
| Aerospace / gas turbine | Dissimilar-alloy weld filler | Sound dissimilar joints |
| Gas turbine | Ring-type components (older engines) | High-temperature strength |
| Chemical process | Dissimilar nickel-alloy welds | Reducing-media resistance |
| Nuclear | Components under radiation | Structural stability |
| Product Form | Standard | Notes |
|---|---|---|
| Welding wire / filler | AWS A5.14 ERNiMo-3 | ASME SFA-5.14; primary form |
| Bar and forgings | ASTM B564 | AMS 5786 |
| Sheet and plate | UNS N10004 | Limited |
| Material designation | UNS N10004 | Dissimilar-welding filler |
Nickel-molybdenum-chromium solid-solution alloy. UNS N10004.
| Alloy | Mo % | Cr % | Primary Role | Best Used For |
|---|---|---|---|---|
| Alloy W | 23–26 | 4–6 | Dissimilar-weld filler | Filler metal for dissimilar nickel-alloy joints; turbine, aerospace |
| Alloy X | 8–10 | 20.5–23 | Wrought high-temp | Gas-turbine combustors, furnace parts |
| Alloy S | 14–16.5 | 14.5–17 | Wrought high-temp | Seal rings, dissimilar filler |
| Alloy B-3 | 27–32 | 1–3 | Wrought corrosion | Hydrochloric acid; reducing media |
| Alloy N | 15–18 | 6–8 | Wrought corrosion | Molten fluoride salts; reactors |




