Hastelloy S is a nickel-based high-temperature alloy with a unique combination of thermal stability, low thermal expansion and oxidation resistance. This datasheet presents the material within the American (ASTM / ASME / UNS) standard system.
Developed for applications involving severely cyclical heating conditions, Hastelloy S retains its strength, ductility and metallurgical integrity after long-time high-temperature exposure. It combines excellent thermal stability with a low coefficient of thermal expansion and excellent oxidation resistance to about 1093 °C (2000 °F), together with good high-temperature and thermal-fatigue strength, and it retains strength and ductility after ageing at 427 to 871 °C (800 to 1600 °F). A small lanthanum (rare-earth) addition promotes oxidation resistance. Strengthening is by solid solution; the alloy is not precipitation-hardened. It is supplied in the solution heat-treated condition.
Typical applications include gas-turbine engine seal rings — where the low thermal-expansion coefficient is particularly important — and other low-stress high-temperature components; the alloy is also an excellent dissimilar-metal filler.
| Property | Value | Unit |
|---|---|---|
| Density | 8.75 | g/cm³ |
| Melting range | 1335–1380 | °C |
| Elastic modulus | 212 | GPa |
| Coefficient of thermal expansion (20–100 °C) | 11.6 | µm/m·°C |
| Thermal conductivity (20 °C) | 9.5 | W/m·K |
| Specific heat (20 °C) | 423 | J/kg·K |
| Structure | Austenitic (FCC), single phase | — |
| Element | Symbol | Min % | Max % | Role in Alloy |
|---|---|---|---|---|
| Nickel | Ni | Balance | — | Base element; high-temperature strength |
| Chromium | Cr | 14.5 | 17.0 | Oxidation resistance |
| Molybdenum | Mo | 14.0 | 16.5 | Solid-solution strengthening |
| Iron | Fe | — | 3.0 | Residual |
| Cobalt | Co | — | 2.0 | Residual |
| Tungsten | W | — | 1.0 | Solid-solution strengthening |
| Aluminium | Al | 0.10 | 0.50 | Oxidation resistance |
| Silicon | Si | 0.20 | 0.75 | Oxidation resistance |
| Manganese | Mn | 0.30 | 1.00 | Deoxidiser |
| Lanthanum | La | 0.01 | 0.10 | Rare-earth; promotes oxidation resistance |
| Carbon | C | — | 0.02 | Low; stability |
Solution heat-treated condition, typical values for UNS N06635.
| Condition | Property | Value |
|---|---|---|
| Solution annealed | Tensile strength (UTS) | ≥835 MPa (121 ksi) |
| Solution annealed | 0.2% yield strength | ≥445 MPa (65 ksi) |
| Solution annealed | Elongation at break | ≥49 % |
| After ageing (427–871 °C) | Strength / ductility | Retained |
| — | Elastic modulus | 212 GPa |
Confirm against the mill test report. The alloy retains strength and ductility after long-time exposure and ageing, which underlies its use under severely cyclical heating.
| Environment | Performance | Notes |
|---|---|---|
| High-temperature oxidation (to 1093 °C) | Excellent | Lanthanum-enhanced scale |
| Thermal cycling / thermal fatigue | Excellent | Low expansion; metallurgical stability |
| Thermal stability after ageing | Excellent | Strength/ductility retained 427–871 °C |
| Dimensional stability | Excellent | Low coefficient of thermal expansion |
| Aqueous corrosion | Moderate | Not the primary design purpose |
The combination of high chromium and molybdenum with a lanthanum addition gives excellent oxidation resistance to about 1093 °C and outstanding thermal stability and thermal-fatigue strength, making the alloy well suited to severely cyclical high-temperature service.
A single-phase solid-solution alloy; not hardenable by precipitation. Properties are set by solution annealing; hardening is by cold work.
Solution Anneal Solution anneal at approximately 1066 °C (1950 °F) followed by air cooling (or rapid cooling) to retain a uniform single-phase structure. Ageing at 538 to 871 °C (1000 to 1600 °F) restores ductility and strength after exposure. The alloy is not strengthened by precipitation; cold work raises strength.
Excellent weldability; readily welded by the gas-tungsten-arc and gas-metal-arc processes. Owing to its toughness and ductility, Hastelloy S is also widely used as an excellent dissimilar-metal filler for joining other high-temperature alloys.
| Welding Process | Applicability | Filler / Consumable |
|---|---|---|
| GTAW / TIG | Excellent | Matching S filler |
| GMAW / MIG | Good | Matching filler |
| As filler metal | Excellent | Dissimilar-metal joints |
Weld on solution-annealed material with clean surfaces; the alloy is also valued as a dissimilar-metal filler.
Machining Guidelines
| Parameter | Recommendation |
|---|---|
| Machinability | Difficult; work-hardens, rigid setups, sharp tooling |
| Speeds | Slow speeds, positive feeds, no dwelling |
| Coolant | Ample coolant |
Forming Processes
| Process | Notes |
|---|---|
| Cold forming | Easily cold worked; work-hardens |
| Hot forming | 872–1149 °C (1600–2100 °F); solution anneal afterward |
| Industry | Typical Components | Key Requirements |
|---|---|---|
| Aero gas turbine | Seal rings, low-stress hot components | Low expansion + thermal fatigue |
| Power generation | High-temperature cyclic components | Thermal stability |
| Welding | Dissimilar-metal filler metal | Ductility + stability |
| High-temperature | Components under cyclical heating | Oxidation + fatigue resistance |
| Product Form | ASTM Standard | AMS |
|---|---|---|
| Plate, sheet and strip | ASTM B435 | AMS 5711 / 5838 |
| Bar, billet and wire | ASTM B435 | AMS 5873 |
| Pipe and tube | UNS N06635 | — |
| Wrought fittings | ASTM B366 | — |
Nickel-chromium-molybdenum high-temperature alloy with lanthanum. UNS N06635.
| Alloy | Cr % | Mo % | Strengthening | Best Used For |
|---|---|---|---|---|
| Hastelloy S | 14.5–17 | 14–16.5 | Solid solution + La | Low-expansion high-temp; gas-turbine seal rings, dissimilar filler |
| Hastelloy X | 20.5–23 | 8–10 | Solid solution | High-temperature oxidation; gas turbines |
| Hastelloy N | 6–8 | 15–18 | Solid solution + M₆C | Molten fluoride salts; molten-salt reactors |
| Hastelloy C-276 | 14.5–16.5 | 15–17 | Solid solution | Reducing media, wet chlorine |
| Hastelloy W | 4–6 | 23–26 | Solid solution | Dissimilar-metal welding filler |




