Nickel & Cobalt Alloys

N19903 Supply Detail

Category

  • Bar and Rod

  • Plate and Sheet

  • Strip

  • Pipe and Tube

  • Wire

  • Welding

  • Powder Material

  • Cast Products

  • Forged Products

  • Fittings

  • Fastening

    Forms & Sizes

    Round Bar:
    φ2–500 mm, 1–6 m length

    Flat/Square Bar:
    4–100 mm thickness/width

    Hex Bar:
    A/F 3–100 mm

    Hollow Bar:
    OD 20–300 mm

    Forms & Sizes

    Sheet:
    0.3–6 mm thickness

    Medium Plate:
    6–25 mm thickness

    Heavy Plate:
    25–100 mm thickness

    Forms & Sizes

    Standard Strip:
    0.05–3 mm thick,
    10–600 mm wide

    Precision strip:
    0.01–0.5 mm thick,
    tight tolerance ±0.005 mm

    Foil:
    0.005–0.1 mm thick

    Forms & Sizes

    Seamless Tube:
    OD 6–450 mm,
    WT 1–50 mm,
    1–12 m length

    Welded Tube:
    OD 10–600 mm,
    WT 1–20 mm

    Capillary Tube:
    OD 1–10 mm,
    WT 0.1–2 mm

    Forms & Sizes

    Wire Form:
    Cold Drawn Wire,
    Bright Wire,
    Spring Wire,
    Fine Wire,
    Ultra-fine Wire

    General Diameter:
    φ0.1–10 mm

    Coil Weight:
    50–500 kg,
    customizable tolerance

    Forms & Sizes

    Solid Wire:
    φ0.8–4.0 mm

    Flux-cored Wire:
    φ1.2–4.0 mm

    Welding Rod:
    φ2.0–5.0 mm

    Forms & Sizes

    Powder Form:
    AM 3D Printing Powder,
    Spherical Powder,
    Gas-atomized Powder,
    Water-atomized Powder

    Particle Size:
    10–150 μm

    Sphericity:
    ≥90% for AM grade

    Forms & Sizes

    Cast Ingot:
    φ200–800 mm

    Precision Casting:
    min wall 0.5 mm

    Cast Pipe:
    OD 100–600 mm,
    WT 10–50 mm

    Forms & Sizes

    Forged Bar:
    Φ35–500 mm

    Forged Ring:
    OD 200–2000 mm

    Forging Weight:
    1–5000 kg

    Forms & Sizes

    Fittings Form:
    Elbow, Tee, Reducer, Flange, Cap, Outlet, Lap Joint

    Size range:
    1/2''–24'' (DN15–DN600)

    Wall thickness:
    Sch10–Sch160, STD, XS, XXS

    Pressure Class:
    150–2500 LB

    Forms & Sizes

    Fastening Form:
    Bolt, Nut, Screw, Stud, Washer, Pin, Rivet

    Metric: M3–M64

    Imperial: #4–2.5''

    Length: 6–500 mm

N19903 Product Description

Overview

N19903 is an age-hardenable nickel-iron-cobalt controlled-expansion alloy. This datasheet presents the material within the American (ASTM / ASME / UNS) standard system.

Developed by Special Metals, N19903 is distinguished by an unusual combination of properties: a constant low coefficient of thermal expansion, a constant modulus of elasticity over a range of temperature, and high strength. It is strengthened by precipitation of γ′ / γ″ (Ni₃(Nb,Ti,Al)) phases during ageing, with the nickel, cobalt and iron together controlling the Curie temperature and the low-expansion behaviour and the niobium, titanium and aluminium providing precipitation hardening. The result is precise dimensional stability with temperature combined with high strength, making the alloy valuable where close clearance control or constant elastic modulus is required. It is used in the solution-treated and aged condition.

Typical applications include rocket-engine thrust chambers, gas-turbine rings and casings for clearance control, steam-turbine bolts, springs, gage blocks and ordnance hardware.

1. Physical Properties

Property Value Unit
Density 8.14 g/cm³
Inflection temperature ~427 °C
Elastic modulus 148 GPa
Coefficient of thermal expansion (20–425 °C) 7.6 µm/m·°C
Thermal conductivity (20 °C) 16.9 W/m·K
Specific heat (20 °C) 442 J/kg·K
Structure Austenitic (FCC)

2. Chemical Composition (wt %)

Element Symbol Min % Max % Role in Alloy
Iron Fe Balance Base element; low-expansion matrix
Nickel Ni 36.0 40.0 Controls expansion / Curie temperature; γ′ matrix
Cobalt Co 13.0 17.0 Controls expansion; raises inflection temperature
Niobium Nb 2.40 3.50 γ′ / γ″ precipitation strengthening
Titanium Ti 1.00 1.85 γ′ precipitation strengthening
Aluminium Al 0.30 1.15 γ′ formation
Silicon Si 0.35 Deoxidiser
Carbon C 0.10 Carbide formation

3. Mechanical Properties

Age-hardened condition, typical values for UNS N19903.

Condition Property Value
Solution treated & aged Tensile strength (UTS) ≥1310 MPa (190 ksi)
Solution treated & aged 0.2% yield strength ≥1035 MPa (150 ksi)
Solution treated & aged Elongation at break ≥12 %
Solution treated & aged Reduction of area ≥30 %
Elastic modulus 148 GPa

Confirm against the mill test report. The alloy maintains a low, constant coefficient of thermal expansion to the inflection temperature (~427 °C) with high strength.

4. Corrosion Resistance

Environment Performance Notes
Dimensional / thermal stability Excellent Constant low CTE; key design feature
High-temperature oxidation Limited Low chromium; not for severe oxidation
Aqueous / general Moderate Low chromium content
Hydrogen environments Use with care Subject to standard precautions
Elevated-temperature strength Excellent Combined with low expansion

The alloy is selected for its controlled expansion, constant modulus and high strength rather than for corrosion resistance; the low chromium content limits high-temperature oxidation resistance, and protective measures may be needed for severe oxidising service.

5. Heat Treatment

A γ′ / γ″ precipitation-hardenable controlled-expansion alloy; strengthened by solution treatment followed by ageing.

Solution Treatment Solution anneal at approximately 845 °C (1550 °F) for about 1 hour and air cool, or per the applicable specification for the product form.

Precipitation Hardening (Ageing) Age at approximately 720 °C (1325 °F) for 8 hours, furnace cool to about 620 °C (1150 °F), hold for a total ageing time of about 18 hours, and air cool — precipitating γ′ / γ″ (Ni₃(Nb,Ti,Al)). A stress-relief and stabilisation cycle may be applied for welded assemblies.

6. Weldability and Joining

Good weldability; can be welded by gas-tungsten-arc, gas-metal-arc, submerged-arc and shielded-metal-arc processes. Welding is done in the solution-annealed condition with post-weld ageing.

Welding Process Applicability Filler / Consumable
GTAW / TIG Good Matching alloy 903 filler
GMAW / MIG Good Matching filler
SAW / SMAW Acceptable Matching consumable

Weld in the solution-annealed condition; apply post-weld stress relief and ageing to develop properties.

7. Machinability and Fabrication

Machining Guidelines

Parameter Recommendation
Preferred condition Solution-annealed for machining, then age
Machinability Difficult; rigid setups, carbide tooling, slow speeds
Coolant Ample coolant

Forming Processes

Process Notes
Cold forming Conventional techniques; heavy-duty lubricants required
Hot forming Readily forged; solution and age afterward

8. Applications

Industry Typical Components Key Requirements
Aerospace / propulsion Rocket-engine thrust chambers Low expansion + high strength
Gas turbine Rings, casings, seals (clearance control) Dimensional stability
Precision Gage blocks, springs, constant-modulus parts Constant CTE / modulus
Power / ordnance Steam-turbine bolts, ordnance hardware Strength + stability

9. Available Product Forms and Standards (ASTM / AMS System)

Product Form Standard / Designation AMS
Bar, rod and forgings UNS N19903 AMS 5803
Sheet, strip and plate UNS N19903
Wire UNS N19903
Material designation UNS N19903 Special Metals product

Nickel-iron-cobalt controlled-expansion alloy. UNS N19903.

10. Comparison with Related Alloys (UNS System)

UNS Type CTE Trend Strengthening Best Used For
N19903 Ni-Fe-Co controlled expansion Low, constant (to ~427 °C) γ′ / γ″ (Nb, Ti, Al) Constant CTE + modulus + strength; thrust chambers, clearance control
N19907 Fe-Ni-Co controlled expansion Low, constant γ′ (Nb, Ti) Higher-strength low-expansion parts (907)
N19909 Fe-Ni-Co controlled expansion Low, constant γ′ (Nb, Ti) Silicon-bearing low-expansion parts (909)
R30783 Ni-Co-Fe + Al Low (~20% < 718) γ′ + β (NiAl) Oxidation-resistant low-expansion alloy (783)
N07718 Ni-Cr-Fe Standard γ′ + γ″ (Nb, Ti) Most-used high-strength superalloy (718)

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