Nickel & Cobalt Alloys

N10003 Supply Detail

Category

  • Bar and Rod

  • Plate and Sheet

  • Strip

  • Pipe and Tube

  • Wire

  • Welding

  • Powder Material

  • Cast Products

  • Forged Products

  • Fittings

  • Fastening

    Forms & Sizes

    Round Bar:
    φ2–500 mm, 1–6 m length

    Flat/Square Bar:
    4–100 mm thickness/width

    Hex Bar:
    A/F 3–100 mm

    Hollow Bar:
    OD 20–300 mm

    Forms & Sizes

    Sheet:
    0.3–6 mm thickness

    Medium Plate:
    6–25 mm thickness

    Heavy Plate:
    25–100 mm thickness

    Forms & Sizes

    Standard Strip:
    0.05–3 mm thick,
    10–600 mm wide

    Precision strip:
    0.01–0.5 mm thick,
    tight tolerance ±0.005 mm

    Foil:
    0.005–0.1 mm thick

    Forms & Sizes

    Seamless Tube:
    OD 6–450 mm,
    WT 1–50 mm,
    1–12 m length

    Welded Tube:
    OD 10–600 mm,
    WT 1–20 mm

    Capillary Tube:
    OD 1–10 mm,
    WT 0.1–2 mm

    Forms & Sizes

    Wire Form:
    Cold Drawn Wire,
    Bright Wire,
    Spring Wire,
    Fine Wire,
    Ultra-fine Wire

    General Diameter:
    φ0.1–10 mm

    Coil Weight:
    50–500 kg,
    customizable tolerance

    Forms & Sizes

    Solid Wire:
    φ0.8–4.0 mm

    Flux-cored Wire:
    φ1.2–4.0 mm

    Welding Rod:
    φ2.0–5.0 mm

    Forms & Sizes

    Powder Form:
    AM 3D Printing Powder,
    Spherical Powder,
    Gas-atomized Powder,
    Water-atomized Powder

    Particle Size:
    10–150 μm

    Sphericity:
    ≥90% for AM grade

    Forms & Sizes

    Cast Ingot:
    φ200–800 mm

    Precision Casting:
    min wall 0.5 mm

    Cast Pipe:
    OD 100–600 mm,
    WT 10–50 mm

    Forms & Sizes

    Forged Bar:
    Φ35–500 mm

    Forged Ring:
    OD 200–2000 mm

    Forging Weight:
    1–5000 kg

    Forms & Sizes

    Fittings Form:
    Elbow, Tee, Reducer, Flange, Cap, Outlet, Lap Joint

    Size range:
    1/2''–24'' (DN15–DN600)

    Wall thickness:
    Sch10–Sch160, STD, XS, XXS

    Pressure Class:
    150–2500 LB

    Forms & Sizes

    Fastening Form:
    Bolt, Nut, Screw, Stud, Washer, Pin, Rivet

    Metric: M3–M64

    Imperial: #4–2.5''

    Length: 6–500 mm

N10003 Product Description

Overview

N10003 is a nickel-molybdenum-chromium alloy developed for service in molten fluoride salts. This datasheet presents the material within the American (ASTM / ASME / UNS) standard system.

Invented at Oak Ridge National Laboratory under the designation INOR-8 as a container material for molten fluoride salts, N10003 is the only standard commercial alloy with demonstrated resistance to corrosion by molten fluoride salt systems at temperatures up to about 704 °C (1300 °F), where corrosion attack in long-duration tests was less than one mil per year. Its chromium content is deliberately kept low — high chromium is attacked by fluoride salts — while molybdenum provides the principal solid-solution strengthening together with good fluoride-salt resistance; the alloy is not strengthened by gamma-prime precipitation. It also offers good oxidation resistance in air to about 982 °C (1800 °F) and good resistance to ageing and embrittlement. It is supplied in the solution-annealed condition.

Typical applications include molten-salt-reactor primary-loop components, thorium fuel-cycle systems, fluoride-based chemical-processing equipment, and containment for molten halides of zirconium, beryllium, lithium, sodium, potassium, thorium or uranium.

1. Physical Properties

Property Value Unit
Density 8.86 g/cm³
Melting range 1300–1370 °C
Elastic modulus 215 GPa
Coefficient of thermal expansion (20–100 °C) 12.6 µm/m·°C
Thermal conductivity (20 °C) 11.6 W/m·K
Specific heat (20 °C) 419 J/kg·K
Structure Austenitic (FCC), single phase + M₆C

2. Chemical Composition (wt %)

Element Symbol Min % Max % Role in Alloy
Nickel Ni Balance Base element
Molybdenum Mo 15.0 18.0 Principal solid-solution strengthening; fluoride-salt resistance
Chromium Cr 6.0 8.0 Oxidation resistance (kept low for salt resistance)
Iron Fe 5.0 Solid-solution; cost
Silicon Si 1.0 Residual
Manganese Mn 0.80 Deoxidiser
Carbon C 0.04 0.08 M₆C carbide formation
Cobalt Co 0.20 Residual

3. Mechanical Properties

Solution-annealed condition, typical values for UNS N10003.

Condition Property Value
Solution annealed Tensile strength (UTS) ≥690 MPa (100 ksi)
Solution annealed 0.2% yield strength ≥275 MPa (40 ksi)
Solution annealed Elongation at break ≥40 %
At 704 °C (1300 °F) High-temperature strength Retained; primary service limit
Elastic modulus 215 GPa

Confirm against the mill test report. High-temperature strength is useful to about 704 °C; long-term service above ~650 °C in reactors is limited by helium and tellurium embrittlement.

4. Corrosion Resistance

Environment Performance Notes
Molten fluoride salts (to 704 °C) Excellent <1 mil/yr; primary application
Molten halides (Zr, Be, Li, Na, K, Th, U) Excellent Salt-container service
Oxidation in air (to 982 °C) Good General high-temperature use
Mineral acids Good Reasonable resistance
Helium / tellurium embrittlement Limitation From Ni transmutation / fission products in reactors

The alloy's low chromium content and high molybdenum give outstanding resistance to molten fluoride and other molten-halide salts — the purpose for which it was designed. In reactor service, helium embrittlement (from nickel transmutation) and grain-boundary embrittlement by tellurium limit long-term high-temperature operation, and the alloy has not been qualified for ASME nuclear construction.

5. Heat Treatment

A single-phase solid-solution alloy with M₆C carbides; not hardenable by precipitation. Properties are set by solution annealing.

Solution Anneal Solution anneal at approximately 1175 °C (2150 °F) and rapidly quench (water or rapid air cool) to dissolve secondary phases and retain a uniform structure. The alloy is not strengthened by heat treatment; cold work raises strength.

6. Weldability and Joining

Good weldability; welded by the gas-tungsten-arc and gas-metal-arc processes with matching filler. Welding is performed on solution-annealed material; clean surfaces are essential.

Welding Process Applicability Filler / Consumable
GTAW / TIG Good Matching Hastelloy N filler
GMAW / MIG Good Matching filler
EBW Good Autogenous or matching filler

Weld on solution-annealed material with matching filler and clean surfaces.

7. Machinability and Fabrication

Machining Guidelines

Parameter Recommendation
Machinability Conventional methods for iron-based alloys; work-hardens
Tooling Carbide; rigid setups, positive feeds
Coolant Water-based coolant for grinding/milling/turning

Forming Processes

Process Notes
Cold forming Good; work-hardens, anneal between heavy operations
Hot forming ~1175–1100 °C; solution anneal afterward

8. Applications

Industry Typical Components Key Requirements
Molten salt reactors Primary-loop piping, vessels, heat exchangers Fluoride-salt corrosion resistance
Thorium fuel cycle Salt-handling equipment Molten-halide resistance
Chemical process Fluoride-based processing equipment Salt + high-temperature resistance
High-temperature Containment for molten halides Corrosion + oxidation resistance

9. Available Product Forms and Standards (ASTM System)

Product Form ASTM Standard Notes
Plate, sheet and strip ASTM B434 UNS N10003
Wrought fittings ASTM B366 UNS N10003
Bar, rod and wire UNS N10003
Original designation INOR-8 Oak Ridge National Laboratory

Nickel-molybdenum-chromium alloy for molten fluoride salts. UNS N10003.

10. Comparison with Related Alloys (UNS System)

UNS Mo % Cr % Strengthening Best Used For
N10003 15–18 6–8 Solid solution + M₆C Molten fluoride salts; molten-salt reactors, halide containment
N10675 27–32 1–3 Solid solution Hydrochloric acid; reducing media (B-3)
N10276 15–17 14.5–16.5 Solid solution Reducing media, wet chlorine (C-276)
N06002 8–10 20.5–23 Solid solution High-temperature oxidation; gas turbines (X)
N06625 8–10 20–23 Solid solution General Ni-Cr-Mo-Nb corrosion / strength (625)

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