Nickel & Cobalt Alloys

2.4642 Supply Detail

Category

  • Bar and Rod

  • Plate and Sheet

  • Strip

  • Pipe and Tube

  • Wire

  • Welding

  • Powder Material

  • Cast Products

  • Forged Products

  • Fittings

  • Fastening

    Forms & Sizes

    Round Bar:
    φ2–500 mm, 1–6 m length

    Flat/Square Bar:
    4–100 mm thickness/width

    Hex Bar:
    A/F 3–100 mm

    Hollow Bar:
    OD 20–300 mm

    Forms & Sizes

    Sheet:
    0.3–6 mm thickness

    Medium Plate:
    6–25 mm thickness

    Heavy Plate:
    25–100 mm thickness

    Forms & Sizes

    Standard Strip:
    0.05–3 mm thick,
    10–600 mm wide

    Precision strip:
    0.01–0.5 mm thick,
    tight tolerance ±0.005 mm

    Foil:
    0.005–0.1 mm thick

    Forms & Sizes

    Seamless Tube:
    OD 6–450 mm,
    WT 1–50 mm,
    1–12 m length

    Welded Tube:
    OD 10–600 mm,
    WT 1–20 mm

    Capillary Tube:
    OD 1–10 mm,
    WT 0.1–2 mm

    Forms & Sizes

    Wire Form:
    Cold Drawn Wire,
    Bright Wire,
    Spring Wire,
    Fine Wire,
    Ultra-fine Wire

    General Diameter:
    φ0.1–10 mm

    Coil Weight:
    50–500 kg,
    customizable tolerance

    Forms & Sizes

    Solid Wire:
    φ0.8–4.0 mm

    Flux-cored Wire:
    φ1.2–4.0 mm

    Welding Rod:
    φ2.0–5.0 mm

    Forms & Sizes

    Powder Form:
    AM 3D Printing Powder,
    Spherical Powder,
    Gas-atomized Powder,
    Water-atomized Powder

    Particle Size:
    10–150 μm

    Sphericity:
    ≥90% for AM grade

    Forms & Sizes

    Cast Ingot:
    φ200–800 mm

    Precision Casting:
    min wall 0.5 mm

    Cast Pipe:
    OD 100–600 mm,
    WT 10–50 mm

    Forms & Sizes

    Forged Bar:
    Φ35–500 mm

    Forged Ring:
    OD 200–2000 mm

    Forging Weight:
    1–5000 kg

    Forms & Sizes

    Fittings Form:
    Elbow, Tee, Reducer, Flange, Cap, Outlet, Lap Joint

    Size range:
    1/2''–24'' (DN15–DN600)

    Wall thickness:
    Sch10–Sch160, STD, XS, XXS

    Pressure Class:
    150–2500 LB

    Forms & Sizes

    Fastening Form:
    Bolt, Nut, Screw, Stud, Washer, Pin, Rivet

    Metric: M3–M64

    Imperial: #4–2.5''

    Length: 6–500 mm

2.4642 Product Description

Overview

2.4642 is a single-phase, austenitic high-chromium nickel–chromium–iron alloy offering outstanding resistance to corrosive aqueous media and high-temperature atmospheres. This datasheet presents the material within the Werkstoff-Nummer designation system.

Its very high chromium content (around 30%) gives outstanding resistance to oxidising chemicals and to high-temperature oxidising gases, while the high nickel content imparts resistance to chloride-induced stress-corrosion cracking and to caustic (alkali) solutions. The alloy has good mechanical properties at both room and elevated temperature paired with high ductility, good metallurgical stability and favorable fabrication characteristics. The low carbon content minimises grain-boundary carbide precipitation, preserving corrosion resistance in the heat-affected zones of welded joints.

The alloy shows very good resistance to fluoride-containing hot nitric acid, excellent resistance to stress-corrosion cracking in chloride- and polythionic-acid-bearing media, and good resistance to oxidation, sulphidation and metal dusting in hot gases. It is the standard material for the primary and secondary loops of nuclear reactors (steam generator tubing), and is used in nitric acid and pickling installations, with operating capability up to approximately 1000 °C.

1. Physical Properties

Property Value Unit
Density 8.20 g/cm³
Melting range 1390–1410 °C
Elastic modulus 211 GPa
Coefficient of thermal expansion (20–100 °C) 14.0 µm/m·°C
Relative magnetic permeability (20 °C) ≤1.01
Maximum operating temperature ~1000 °C
Structure Single-phase austenitic (FCC)

2. Chemical Composition (wt %)

Element Symbol Min % Max % Role in Alloy
Nickel Ni 58.0 Austenitic FCC matrix; SCC + alkali resistance
Chromium Cr 27.0 31.0 Oxidation + oxidising-acid resistance; passive film
Iron Fe 7.0 11.0 Solid-solution element
Manganese Mn 0.50 Deoxidiser
Silicon Si 0.50 Deoxidiser
Copper Cu 0.50 Residual
Carbon C 0.05 Low; minimises HAZ carbide precipitation
Sulphur S 0.015 Residual impurity

3. Mechanical Properties

Typical values; confirm against the inspection certificate (EN 10204) for each delivery.

Condition Property Value
Solution-annealed Tensile strength (Rm) 590–750 MPa
Solution-annealed 0.2% proof strength (Rp0.2) ≥240 MPa
Solution-annealed 1.0% proof strength (Rp1.0) ≥280 MPa
Solution-annealed Elongation ≥30 %
Elastic modulus 211 GPa

The alloy is a single-phase solid-solution material; it is not age-hardenable. Higher strength is obtained by cold work. Mechanical properties are given as a range with a 1.0% proof value, per the European convention.

4. Corrosion Resistance

Environment Performance Notes
Nitric acid (HNO₃) Outstanding Very high chromium content
Fluoride-containing hot nitric acid Very Good Pickling installations
Caustic / alkali Outstanding High nickel content
Chloride stress-corrosion cracking Outstanding High nickel content
Polythionic-acid SCC Excellent Resistant in service environments
High-temperature oxidation Outstanding Stable Cr₂O₃ scale
Sulphidation / metal dusting Good High Cr + Ni in hot gases

5. Heat Treatment

The alloy is a single-phase, solid-solution material and is NOT age-hardenable. Heat treatment is for solution annealing only.

Solution Anneal Purpose: Dissolves secondary phases, restores maximum corrosion resistance and ductility, recrystallises cold-worked structure. Typically 1040–1100 °C followed by rapid cooling (water quench) to retain the single-phase structure. A thermal treatment (e.g. ~715 °C) is sometimes applied to nuclear tubing to optimise the grain-boundary carbide structure and stress-corrosion-cracking resistance.

Cold work is used to increase strength where required; a subsequent solution anneal removes the effects of cold work.

6. Weldability and Joining

Excellent weldability; the low carbon content preserves corrosion resistance in the heat-affected zone. Matched-composition welding products give as-welded resistance in oxidising and alkali environments.

Welding Process Applicability Filler / Consumable
GTAW / TIG Excellent Matching Ni-Cr-29-Fe filler
GMAW / MIG Excellent Matching Ni-Cr-29-Fe filler
SMAW / stick Excellent Matching Ni-Cr-Fe electrode

The welding products are also used for dissimilar-metal and overmatched welding. No post-weld heat treatment is normally required.

7. Machinability and Fabrication

Machining Guidelines

Parameter Recommendation
Work hardening High rate (typical of Ni-Cr-Fe alloys); rigid setup, sharp tooling, positive rake
Cutting Low speed, sufficient feed/depth to cut below the work-hardened layer
Coolant Ample flood coolant
Preferred condition Solution-annealed

Forming Processes

Process Notes
Cold forming Readily cold-formed; high work-hardening rate; intermediate solution anneal for heavy reductions
Hot forming ~1150–950 °C; followed by rapid cooling to retain single-phase structure
Tube / bar Standard product forms for steam generator and process service

8. Applications

Industry Typical Components Key Requirements
Nuclear power Steam generator tubes, tubesheets, baffles Chloride/alkali SCC resistance; reactor loops
Chemical processing Nitric acid plant, pickling tanks and coils Nitric / HF acid resistance
Heat treatment Furnace components, retorts, fixtures High-temperature oxidation resistance
Petrochemical High-temperature process equipment Oxidation + metal-dusting resistance
Pollution control Acid-bearing process hardware Oxidising-media resistance

9. Available Product Forms and Standards

Product Form DIN Standard EN / ISO Standard
Sheet, plate and strip DIN 17742 / DIN 17750 EN ISO 6208
Rod and bar DIN 17742 / DIN 17752
Wire DIN 17753
Seamless tube DIN 17751 EN ISO 6208
Forgings DIN 17754
Technical delivery VdTÜV-Wbl. 485

Qualified for sour-service per ISO 15156-3 / NACE MR0175.

10. Comparison with Related Alloys (Werkstoff-Nummer System)

W.Nr. Ni % Cr % Fe % Other Best Used For
2.4642 ≥58 27–31 7–11 Nuclear SG tubing; nitric acid; high-temp oxidation
2.4816 ≥72 14–17 6–10 General Ni-Cr-Fe; high-temperature service
2.4851 58–63 21–25 bal Al 1–1.7 High-temperature oxidation resistance
2.4856 ≥58 20–23 ≤5 Mo 8–10; Nb 3.15–4.15 Seawater; chemical process; high strength
1.4876 30–34 19–23 bal Al, Ti High-temperature Fe-Ni-Cr

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