Nickel & Cobalt Alloys

2.4665 Supply Detail

Category

  • Bar and Rod

  • Plate and Sheet

  • Strip

  • Pipe and Tube

  • Wire

  • Welding

  • Powder Material

  • Cast Products

  • Forged Products

  • Fittings

  • Fastening

    Forms & Sizes

    Round Bar:
    φ2–500 mm, 1–6 m length

    Flat/Square Bar:
    4–100 mm thickness/width

    Hex Bar:
    A/F 3–100 mm

    Hollow Bar:
    OD 20–300 mm

    Forms & Sizes

    Sheet:
    0.3–6 mm thickness

    Medium Plate:
    6–25 mm thickness

    Heavy Plate:
    25–100 mm thickness

    Forms & Sizes

    Standard Strip:
    0.05–3 mm thick,
    10–600 mm wide

    Precision strip:
    0.01–0.5 mm thick,
    tight tolerance ±0.005 mm

    Foil:
    0.005–0.1 mm thick

    Forms & Sizes

    Seamless Tube:
    OD 6–450 mm,
    WT 1–50 mm,
    1–12 m length

    Welded Tube:
    OD 10–600 mm,
    WT 1–20 mm

    Capillary Tube:
    OD 1–10 mm,
    WT 0.1–2 mm

    Forms & Sizes

    Wire Form:
    Cold Drawn Wire,
    Bright Wire,
    Spring Wire,
    Fine Wire,
    Ultra-fine Wire

    General Diameter:
    φ0.1–10 mm

    Coil Weight:
    50–500 kg,
    customizable tolerance

    Forms & Sizes

    Solid Wire:
    φ0.8–4.0 mm

    Flux-cored Wire:
    φ1.2–4.0 mm

    Welding Rod:
    φ2.0–5.0 mm

    Forms & Sizes

    Powder Form:
    AM 3D Printing Powder,
    Spherical Powder,
    Gas-atomized Powder,
    Water-atomized Powder

    Particle Size:
    10–150 μm

    Sphericity:
    ≥90% for AM grade

    Forms & Sizes

    Cast Ingot:
    φ200–800 mm

    Precision Casting:
    min wall 0.5 mm

    Cast Pipe:
    OD 100–600 mm,
    WT 10–50 mm

    Forms & Sizes

    Forged Bar:
    Φ35–500 mm

    Forged Ring:
    OD 200–2000 mm

    Forging Weight:
    1–5000 kg

    Forms & Sizes

    Fittings Form:
    Elbow, Tee, Reducer, Flange, Cap, Outlet, Lap Joint

    Size range:
    1/2''–24'' (DN15–DN600)

    Wall thickness:
    Sch10–Sch160, STD, XS, XXS

    Pressure Class:
    150–2500 LB

    Forms & Sizes

    Fastening Form:
    Bolt, Nut, Screw, Stud, Washer, Pin, Rivet

    Metric: M3–M64

    Imperial: #4–2.5''

    Length: 6–500 mm

2.4665 Product Description

Overview

2.4665 is the German material number for a nickel-chromium-iron-molybdenum high-temperature alloy. This datasheet presents the material within the Werkstoff-Nummer (DIN / EN) designation system.

A solid-solution-strengthened superalloy of the Ni-Cr-Fe-Mo family, 2.4665 possesses an exceptional combination of oxidation resistance, fabricability and high-temperature strength, with creep and stress-rupture properties useful to about 1200 °C. The high nickel content improves resistance to carburisation, nitridation and chlorination; chromium provides oxidation and carburisation resistance; and molybdenum and tungsten enhance high-temperature creep strength. It is exceptionally resistant to stress-corrosion cracking in petrochemical applications and retains good ductility after prolonged exposure at 650, 760 and 870 °C. With excellent forming and welding characteristics, it is supplied in the solution heat-treated condition.

Typical applications include gas-turbine combustion-zone components — transition ducts, combustor cans, spray bars and flame holders — afterburners, tailpipes and cabin heaters, and industrial-furnace rolls, retorts, baffles and muffles.

1. Physical Properties

Property Value Unit
Density 8.22 g/cm³
Melting range 1260–1355 °C
Elastic modulus 205 GPa
Coefficient of thermal expansion (20–100 °C) 13.9 µm/m·°C
Thermal conductivity (20 °C) 9.1 W/m·K
Specific heat (20 °C) 486 J/kg·K
Structure Austenitic (FCC), single phase

2. Chemical Composition (wt %)

Element Symbol Min % Max % Role in Alloy
Nickel Ni Balance Base element; carburisation / nitridation resistance
Chromium Cr 20.5 23.0 Oxidation / carburisation resistance
Iron Fe 17.0 20.0 Solid-solution; cost-effectiveness
Molybdenum Mo 8.0 10.0 High-temperature creep strength
Cobalt Co 0.50 2.50 High-temperature strength
Tungsten W 0.20 1.0 Creep / oxidation resistance
Manganese Mn 1.0 Deoxidiser
Silicon Si 1.0 Oxidation resistance
Carbon C 0.05 0.15 Carbide strengthening

3. Mechanical Properties

Solution heat-treated condition, per EN reference data for W.Nr. 2.4665.

Condition Property Value
Solution annealed Tensile strength (Rm) ≥755 MPa
Solution annealed 0.2% proof strength (Rp0.2) ≥385 MPa
Solution annealed Elongation (A5) ≥45 %
At elevated temperature Creep / rupture strength Useful to ~1200 °C
Elastic modulus 205 GPa

Values per EN reference data; the alloy retains good ductility after long-time exposure at high temperature. Confirm against the inspection certificate (EN 10204).

4. Corrosion / Oxidation Resistance

Environment Performance Notes
High-temperature oxidation (to ~1200 °C) Excellent Adherent chromia scale
Carburisation Excellent Best among Ni / Co alloys
Reducing / neutral atmospheres Excellent Balanced resistance
Hot corrosion / molten salts Very Good Low attack in tests
Stress-corrosion cracking Excellent Petrochemical service

The balanced chromium, molybdenum and nickel content gives an exceptional combination of resistance to oxidizing, reducing and neutral atmospheres at high temperature, with outstanding carburisation resistance and excellent resistance to stress-corrosion cracking.

5. Heat Treatment

A single-phase solid-solution alloy; not hardenable by precipitation. Properties are set by solution annealing.

Solution Anneal Solution anneal sheet and tube at approximately 1175 °C and rapidly cool (air or water). Bar and forgings are held at about 1177 °C long enough to bring the section to temperature, then rapidly cooled. The alloy is not strengthened by heat treatment; all hot- or cold-worked parts should be annealed and rapidly cooled to restore the best balance of properties.

6. Weldability and Joining

Excellent weldability; welded by shielded-metal-arc, gas-tungsten-arc and gas-metal-arc processes, and resistance welding, with matching filler. Welding is performed on solution-annealed material.

Welding Process Applicability Filler / Consumable
GTAW / TIG Excellent Matching filler
GMAW / MIG Good Matching filler
SMAW / stick Good Matching electrode

Weld on solution-annealed material with matching filler and clean surfaces.

7. Machinability and Fabrication

Machining Guidelines

Parameter Recommendation
Machinability Difficult; work-hardens, rigid setups, sharp tooling
Speeds Slow speeds, positive feeds, no dwelling
Coolant Ample coolant

Forming Processes

Process Notes
Cold forming Good ductility; work-hardens, anneal between heavy operations
Hot forming ~1177 °C (held to temperature); anneal and rapid-cool afterward

8. Applications

Industry Typical Components Key Requirements
Aero gas turbine Combustor cans, transition ducts, flame holders Oxidation + high-temperature strength
Propulsion Afterburners, tailpipes, cabin heaters Thermal + oxidation resistance
Industrial furnaces Rolls, retorts, baffles, muffles Oxidizing/reducing/neutral atmospheres
Petrochemical High-temperature equipment Stress-corrosion-cracking resistance

9. Available Product Forms and Standards (DIN / EN System)

Product Form DIN / EN Standard Notes
Plate, sheet and strip DIN 17750 · W.Nr. 2.4665 NiCr22Fe18Mo
Bar, rod and forgings DIN 17752 · W.Nr. 2.4665
Seamless pipe and tube DIN 17751 · W.Nr. 2.4665
Inspection documents EN 10204

Nickel-chromium-iron-molybdenum high-temperature alloy. W.Nr. 2.4665 (NiCr22Fe18Mo).

10. Comparison with Related Alloys (Werkstoff-Nummer System)

W.Nr. Cr % Mo % Fe % Best Used For
2.4665 20.5–23 8–10 17–20 Ni-Cr-Fe-Mo high-temp; gas-turbine combustors, furnace parts
2.4856 20–23 8–10 ≤5 General Ni-Cr-Mo-Nb corrosion / strength (625)
2.4819 14.5–16.5 15–17 4–7 Reducing media, wet chlorine (C-276)
2.4633 24–26 8–11 High-temperature oxidation; aluminium-bearing (602 CA)
1.4876 19–23 balance General high-temperature service (800H)

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